專利名稱：：包含第爾斯一阿爾德濕潤(rùn)劑的加顏料調(diào)色母料的制作方法包含第爾斯-阿爾德濕潤(rùn)劑的加顏料調(diào)色母料本發(fā)明涉及水性加顏料調(diào)色母料的濕潤(rùn)劑。水性加顏料調(diào)色母料用于各種各樣的工業(yè)應(yīng)用，例如印刷墨、漆、漿粕和紙、涂料、和紡織品的制造，以提供著色。水性加顏料調(diào)色母料含有濕潤(rùn)劑，以減少或消除由于噴嘴前端千燥引起的噴嘴堵塞。然而，濕潤(rùn)劑顯著降低了用顏料母料調(diào)色的漆的干燥速率。目前商業(yè)上可得的水性調(diào)色母料含有乙二醇作為濕潤(rùn)劑，其表現(xiàn)同水性調(diào)色料母料中的濕潤(rùn)劑一樣，但它是中等揮發(fā)性的，其25。C蒸氣壓實(shí)質(zhì)上高于1.3Pa。同所有揮發(fā)性有一幾液體一樣，乙二醇現(xiàn)在也吸引了環(huán)境關(guān)注(不贊成)。進(jìn)而，乙二醇濕潤(rùn)劑在潮濕氛圍中對(duì)光澤水平有負(fù)面影響。因此，本發(fā)明的目的是提供無(wú)揮發(fā)性有機(jī)化合物(VOC)、對(duì)光澤水平無(wú)負(fù)面影響的、加有機(jī)和無(wú)機(jī)顏料的調(diào)色母料。已經(jīng)發(fā)現(xiàn)，用第爾斯-阿爾德反應(yīng)產(chǎn)物官能化的聚醚提供了無(wú)VOC濕潤(rùn)劑。因此，本發(fā)明涉及加顏料的調(diào)色母料，包含a)穩(wěn)定的顏料；b)可通過(guò)在150260。C的溫度在一種多不飽和化合物與一種共反應(yīng)物之間進(jìn)行第爾斯-阿爾德反應(yīng)得到的濕潤(rùn)劑化合物，該共反應(yīng)物有化學(xué)式RiXOC-CH=CH-COXR2或CH2=CH-COXR3或CH2=CH(CH3)-COXR3，式中X是氧或-NH-,且式中和R2中至少一個(gè)是一種聚醚片斷，Ri和R2中任何另一個(gè)是一種聚醚片斷或氫，而R3是一種聚醚片斷。式R1XOC-CH=CH-COXR2的化合物可以通過(guò)用一種羥基官能聚醚打開(kāi)馬來(lái)酸酐來(lái)制備。多不飽和化合物是，例如，山梨酸(2,4-己二烯酸)、(β-lonone(2,6,6-三曱基環(huán)己烯基一丁烯一2-酮)、月才圭烯(7—曱基—3-亞曱基-1，6-辛二烯)或較好多不飽和油。β多不飽和油較好是干性油，包括例如桐油、奧氣油、脫水蓖麻油、紫蘇子油、亞麻子油、聚合亞麻子油、大豆油、葵花子油、紅花油、棉子油、妥爾油、魚(yú)油等以及從其得到的酯交換油。酯交換較好是用一種C1-C20烷醇較好甲醇或聚醚或聚醚胺(jeffamine)進(jìn)行的。用來(lái)衍生以上加合物的干性油含有脂肪酸例如9,11，13-十八碳三烯酸(桐酸)或4-氧代-9,11,13-十八石友三烯酸(十八碳三烯-4-酮酸、奧氣油)或其酯。有不止2個(gè)雙鍵的脂肪酸是較好的。因此，較好的是式I的濕潤(rùn)劑化合物<formula>seeoriginaldocumentpage5</formula>式中a、b和c各自獨(dú)立地是0或1,先決條件是當(dāng)b和c為0時(shí)a為1;Y當(dāng)a、b和c為1時(shí)是-CH2-;且Y當(dāng)a為l而b和c為0時(shí)是d-(320烷基或一種聚醚片斷；R4是<formula>seeoriginaldocumentpage5</formula>X是氧或-NH-；R5和R6是氫或R4或多不飽和脂肪酸片斷；Ri和R2中至少一個(gè)是一種聚醚片斷，且R!和R2中任何另一個(gè)是一種聚醚片斷或氫；R3是一種聚醚片斷；R7是氫或甲基；W是-(CH2)P_或-(CH2)P,-CO-(CH2)q_;n是0~20、較好4~10;m是(2n-2)~2n;p是1~20、4交好4~10;p，是1~20、較好24;q是1~20、較好4~10。聚醚片斷這一術(shù)語(yǔ)表示該多不飽和油用一種聚醚或一種聚醚胺酯交換衍生的一種片斷。聚醚這一術(shù)語(yǔ)表示一種含有多個(gè)醚基而且有羥端基的大分子，例如HO-CH2CH2-(O-CH2CH2)y-OR或HO-CH2CH2CH2-(O-CH2CH2CH2)y-OR或HO_CH2CH(CH3)-(O-CH2CH(CH3))y-OR或混合的EO/PO-聚醚；其中y—般是022、4交好3~22、最好3~13,且R是烷基、較好d-C6烷基、最好曱基或乙基。聚醚胺這一術(shù)語(yǔ)表示一種含有多個(gè)醚基而且有胺端基的大分子，例如H2N-CH2CH2-(O-CH2CH2)y-OR或H2N-CH2CH2CH2-(O-CH2CH2CH2)y-OR或H2N-CH2CH(CH3)-(O-CH2CH(CH3))y-OR或混合的EO/PO-聚醚胺，其中y—般是0~22、較好3~22、最好3~13,且R是烷基、較好C廣Q烷基；最好甲基或乙基。顏料可以是有機(jī)顏料和無(wú)機(jī)顏料，例如酞菁類、偶氮顏料類、喹吖啶酮類或炭黑、二氧化鈦和鐵氧化物。調(diào)色料中顏料的重量百分率因所需要的調(diào)色料的強(qiáng)度而異，是諸如10-75wt。/。不等。在精心地要求一種調(diào)色料具有低強(qiáng)度的情況下(例如，在只想要輕微灰白色調(diào)的情況下)，況下，通常還向該調(diào)色料中添加中性固體，而這些中性微粒通常簡(jiǎn)稱為"增充劑，，(extender)微粒。為了本發(fā)明之目的，將認(rèn)為任何必要的增充劑微粒就是顏料微粒。典型的增充劑包括粘土、白堊、滑石、重晶石和娃石。該顏料是用例如脂肪酸改性乳化劑如EFKA6225、EFKA6220或EFKA6230或者分散劑如EFKA5071、EFKA4550、EFKA4570、EFKA4580等穩(wěn)定的。按照本發(fā)明的濕潤(rùn)劑特別適用于顏料母料的生產(chǎn)。為此目的，將按照本發(fā)明的化合物導(dǎo)入水中，并在攪拌下添加要分散的顏料。此外，這些顏料母料還可以含有基料載劑和/或其它輔助物質(zhì)。這些顏料母料可以摻入各種基料載劑例如醇酸樹(shù)脂、聚酯樹(shù)脂、丙烯酸酯樹(shù)脂、聚氨酯樹(shù)6脂或環(huán)氧樹(shù)脂等中。按照本發(fā)明的濕潤(rùn)劑也適用于噴墨用墨的生產(chǎn)。實(shí)施例本發(fā)明進(jìn)一步用以下實(shí)施例說(shuō)明。中間體A和B的一4l程序中間體A:將1份苛性鉀溶解于15份甲醇中。添加75份奧氣油。該混合物在氮?dú)夥諊略诔貏×覕嚢杓s1h。在約1天的靜置時(shí)間之后，將下相作為化學(xué)廢物拋棄。主要由相應(yīng)脂肪酸的甲酯組成的上相不進(jìn)一步精制就可以用于隨后的實(shí)馬全。以相同方式合成基于桐油的中間體B。濕潤(rùn)劑合成「I的一般程序?qū)ⅠR來(lái)酸酐和一種羥基官能聚醚在氮?dú)夥諊轮糜谝粋€(gè)三口燒瓶中并加熱到120°C。在這一溫度添加一種不飽和原料(就第爾斯-阿爾德反應(yīng)而言，在作為雙烯的反應(yīng)性)。將該反應(yīng)混合物加熱約5h,可高達(dá)180190。C。詳細(xì)摩爾比見(jiàn)表l。濕潤(rùn)劑合成「III的一般程序?qū)⒁环N不飽和原料(就第爾斯-阿爾德反應(yīng)而言，有作為雙烯的反應(yīng)性)和一種(甲基)丙烯酸官能聚醚的混合物在氮?dú)夥諊轮糜谝粋€(gè)三口燒瓶中，并加熱約5h,達(dá)到1801卯。C。詳細(xì)摩爾比見(jiàn)表2。濕潤(rùn)劑合成「IIIl的一般程序?qū)⒅虚g體A(B,分別)、一種單OH官能聚醚和0.5wt。/。對(duì)甲苯磺酸的混合物在氮?dú)夥諊轮糜谝粋€(gè)三口燒^f瓦中并加熱約5h,達(dá)到180-190°C。在冷卻到12(TC之后，添加馬來(lái)酸酐。將這種混合物再加熱約3h,達(dá)到180190。C。詳細(xì)摩爾比見(jiàn)表3。所得到的產(chǎn)物顯示出作為濕潤(rùn)劑的優(yōu)異性能。通過(guò)添加催干劑和/或酸性基團(tuán)的離子化可以提高該性能。脂肪酸胺縮合物尤其適合作為離子化劑。所使用原材料的化學(xué)組成代號(hào):PEG-200:聚乙二醇;MW~200/molPEG-600:聚乙二醇;MW~600/molMPPG-200:聚丙二醇單曱醚；Mw~200g/molMPEG-350:聚乙二醇單甲醚；Mw~350g/molMPEG-500:聚乙二醇單甲醚；Mw~500g/molMPEG-750:聚乙二醇單甲醚；Mw~750g/molMPEG-1000:聚乙二醇單甲醚；Mw~1000g/molPLURAFACLF401:非離子型表面活性劑，BASF公司PLURAFACLF600:非離子型表面活性劑，BASF公司BISOMERMPEG350MA:甲基丙烯酸-甲基聚乙二醇酯，平均分子量350g/molBISOMERMPEG550MA:甲基丙烯酸-甲基聚乙二醇酯，平均分子量550g/molBISOMERMPEG1000MA:甲基丙烯酸-甲基聚乙二醇酯，平均分子量1000g/molMn催干劑NuodexWEBManganese9,Elementis公司Ce催干劑ValirexCe10%D60Co催干劑環(huán)烷酸鈷，Aldrich公司離子化劑脂肪酸胺縮合物和類似化合物表1濕潤(rùn)劑合成I的一般程序<table><row><column>實(shí)施例</column><column>馬來(lái)酸酐</column><column>聚醚</column><column>多不飽和化合物</column></row><row><column>1</column><column>7．5g</column><column>15．0gPEG一200</column><column>37．5g桐油</column></row><row><column>2</column><column>7．5g</column><column>26．3gMPEG一350</column><column>37．5g桐油</column></row><row><column>3</column><column>7．5g</column><column>37．5gMPEG一500</column><column>37．5g桐油</column></row><row><column>4</column><column>7．5g</column><column>15．0gPEG一200</column><column>37．5g奧氣油</column></row><row><column>5</column><column>7．5g</column><column>26．3gMPEG-350</column><column>37．5g奧氣油</column></row><row><column>6</column><column>7．5g</column><column>37．5gMPEG-500</column><column>37．5g奧氣油</column></row><row><column>7</column><column>7．5g</column><column>18．4gMPEG一500</column><column>37．5g桐油</column></row><row><column>8</column><column>7．5g</column><column>37．5gMPEG一500</column><column>39．4g中間體B</column></row><row><column>9</column><column>7．5g</column><column>37．5gMPEG一500</column><column>39．4g中間體A</column></row><row><column>10</column><column>7．5g</column><column>37．5gMPEG一500</column><column>2，j．3g中間體B</column></row><row><column>11</column><column>7．5g</column><column>37．5gMPEG一500</column><column>23．3g中間體A</column></row><row><column>12</column><column>7．5g</column><column>46．7gPlurafacLF401</column><column>37．5g桐油</column></row><row><column>13</column><column>7．5g</column><column>46．7gPlurafacLF401</column><column>37-5g奧氣油</column></row><row><column>14</column><column>7．5g</column><column>29．9gPlurafacLF600</column><column>37．5g奧氣油</column></row><row><column>15</column><column>10．0g</column><column>20．0gPEG一200</column><column>31-2g中間體A</column></row><row><column>16</column><column>10．0g</column><column>20．0gPEG-200</column><column>31．2g中間體B</column></row><row><column>17</column><column>2．5g</column><column>24．0gPlurafacLF600</column><column>39．4g中間體A</column></row><row><column>18</column><column>2．5g</column><column>37．5gPlurafacLF401</column><column>7．3g中間體B</column></row><row><column>19</column><column>3．0g</column><column>18．4gPEG-600</column><column>3()．0g桐油</column></row><row><column>20</column><column>3．0g</column><column>18．4gPEG-600</column><column>3()．0g奧氣油</column></row><row><column>21</column><column>2．7g</column><column>27．5gMPEG-1000</column><column>40．5g桐油</column></row><row><column>22</column><column>2．7g</column><column>27．5gMPEG一1000</column><column>4015g奧氣油</column></row><row><column>23</column><column>7．5g</column><column>26．3gMPEG一350</column><column>2；．3g中間體A</column></row><row><column>24</column><column>7．5g</column><column>26．3gMPEG一350</column><column>23．3g中間體B</column></row><row><column>25</column><column>7．5g</column><column>75．0gMPEG一1000</column><column>23．3g中間體B</column></row><row><column>26</column><column>7．5g</column><column>75．0gMPEG一1000</column><column>23．3g中間體A</column></row><row><column>27</column><column>7．5g</column><column>56．3gMPEG一750</column><column>23．3g中間體B</column></row><row><column>28</column><column>7．5g</column><column>56．3gMPEG一750</column><column>23．3g中間體A</column></row><table>表2:濕潤(rùn)劑合成II的一般程序<table><row><column>實(shí)施例</column><column>(甲基)丙烯酸官能聚醚</column><column>多不飽和化合物</column></row><row><column></column><column>29</column><column>42.10gBisomerMPEG500MA</column><column>37-5g桐油</column></row><row><column></column><column>30</column><column>42.10gBisomerMPEG500MA</column><column>37.5g奧氣油</column></row><row><column></column><column>31</column><column>22.8gBisomerMPEG1000MA</column><column>37-5g桐油</column></row><row><column></column><column>32</column><column>22.8gBisomerMPEG1000MA</column><column>37-59奧氣油</column></row><row><column></column><column>33</column><column>34.3gBisomerMPEG550MA</column><column>5.的山梨酸</column></row><row><column></column><column>34</column><column>34,3gBisomerMPEG550MA</column><column>10.1gB-lonone</column></row><row><column></column><column>35</column><column>34.3gBisomerMPEG550MA</column><column>月桂烯</column></row><row><column></column><column>36</column><column>34.0gBisomerMPEG350MA</column><column>25.0g桐油</column></row><row><column></column><column>37</column><column>30.0gBisomerMPEG1000MA</column><column>8-5g中間體A</column></row><row><column></column><column>38</column><column>30.0gBisomerMPEG1000MA</column><column>8-5g中間體B</column></row><row><column></column><column>39</column><column>45.10gBisomerMPEG550MA</column><column>25.0g中間體A</column></row><row><column></column><column>40</column><column>45.10gBisomerMPEG550MA</column><column>25.0g中間體B</column></row><row><column></column><column>41</column><column>34.0gBisomerMPEG350MA</column><column>25.0g奧氣油</column></row><table>山梨酸=2,4-己二烯酸p-lonone=2，6，6-三曱基環(huán)己烯基-丁烯-2-酮月才主烯=7-甲基-3—亞曱基一1,6—辛二烯表3:濕潤(rùn)劑合成III的一般程序<table><row><column>實(shí)施例</column><column>馬來(lái)酸酐</column><column>聚醚</column><column>多不飽和化合物</column><column>催干劑</column><column>離子化劑</column></row><row><column>42</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體B</column></row><row><column>43</column><column>2.8g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體B</column></row><row><column>44</column><column>4.2g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體B</column></row><row><column>45</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體A</column></row><row><column>46</column><column>2.8g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體A</column></row><row><column>47</column><column>4.2g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體A</column></row><row><column>48</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體B</column></row><row><column>49</column><column>2.8g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體B</column></row><row><column>50</column><column>4.2g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體B</column></row><row><column>51</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體A</column></row><row><column>52</column><column>2.8g</column><column>29.0g</column><column>MPEG掘</column><column>21.0g中間體A</column></row><row><column>53</column><column>4.2g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體A</column></row><row><column>54</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體B</column><column></column><column>3.24g</column></row><row><column>55</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.Og中間體A</column><column></column><column>3.24g</column></row><row><column>56</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體B</column><column>11.3gCo催干劑</column></row><row><column>57</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體A</column><column>11.3gCo催干劑</column></row><row><column>58</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.Og中間體B</column><column>11.3gCo催干劑</column><column>3.24g</column></row><row><column>59</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.Og中間體A</column><column>11.3gCo催干劑</column><column>3.24g</column></row><row><column>60</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體B</column><column>6.7gCe催干劑</column></row><row><column>61</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體A</column><column>6.7gCe催干劑</column></row><row><column>62</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體B</column><column>6.7gCe催干劑</column><column>3.24g</column></row><row><column>63</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.Og中間體A</column><column>6.7gCe催干劑</column><column>3.24g</column></row><row><column>64</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體B</column><column>7.4gMn催干劑</column></row><row><column>65</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體A</column><column>7.4gMn催干劑</column></row><row><column>66</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體B</column><column>7.4gMrH崔干劑</column><column>3.24g</column></row><row><column>67</column><column>1.4g</column><column>42.0g</column><column>MPEG-500</column><column>21.0g中間體A</column><column>7.4gMn催干劑</column><column>3.24g</column></row><row><column>68</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體B</column><column>9.0gCo催干劑</column></row><row><column>69</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體A</column><column>9.0gCo催干劑</column></row><row><column>70</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體B</column><column>9.0gCo催干劑</column><column>3.24g</column></row><row><column>71</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體A</column><column>9.0gCo催干劑</column><column>3.24g</column></row><row><column>72</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體B</column><column>5.3gCe催干劑</column></row><row><column>73</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.Og中間體A</column><column>5.3gCe催干劑</column></row><row><column>74</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體B</column><column>5.3gCe催干劑</column><column>3.24g</column></row><row><column>75</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體A</column><column>5.3gCe催干劑</column><column>3.24g</column></row><row><column>76</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體B</column><column>5.9gMn催干劑</column></row><row><column>77</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.Og中間體A</column><column>5.9gMn催干劑</column></row><row><column>78</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中間體B</column><column>5.9gMn催干劑</column><column>3.24g</column></row><row><column>79</column><column>1.4g</column><column>29.0g</column><column>MPEG-350</column><column>21.0g中問(wèn)體A</column><column>5.9gMn催干劑</column><column>3.24g</column></row><row><column>80</column><column>7.5g</column><column>15.5g</column><column>MPPG200</column><column>23.3g中間體A</column></row><row><column>81</column><column>7.5g</column><column>15.5g</column><column>MPPG200</column><column>23.3g中間體B</column></row><table>加顏料的調(diào)色母料的制備基于通用著色劑指導(dǎo)配方(見(jiàn)比較例2)的顏料母料。固體載體(濕潤(rùn)劑)、顏料和分散劑之間的比例等于該指導(dǎo)配方。使用追加軟化水使該母料達(dá)到恰當(dāng)研磨粘度并在一臺(tái)Scandex(漆振蕩器)中用玻璃珠將其研磨1h。市售產(chǎn)品"Nuosperse2000"和"HumectantGRB2"在比較例3和4中用來(lái)作為除純長(zhǎng)油醇酸樹(shù)脂[母料](見(jiàn)比較例1)一"理想標(biāo)準(zhǔn)物，，一外的參考物，和在比較例2中用來(lái)作為這種應(yīng)用的現(xiàn)行指導(dǎo)配方。<table></column></row><row><column>-</column><column>比較例l</column><column>比庫(kù)交例2</column><column>比專交例3</column><column>比凈交例4</column></row><row><column>Nuosperse2000[水中700/0]</column><column>-</column><column>-</column><column>20.94</column><column>-</column></row><row><column>HumectantGRB2</column><column>一</column><column>-</column><column>-</column><column>18.0</column></row><row><column>LO.AIkydTransparent</column><column>26.75</column><column>-</column><column>—</column><column>-</column></row><row><column>聚乙二醇200</column><column>-</column><column>8.49</column><column>-</column><column>-</column></row><row><column>三聚丙二醇甲基醚</column><column>-</column><column>8.49</column><column>-</column><column>-</column></row><row><column>EFKA-6225</column><column>6.50</column><column>6.13</column><column>5.52</column><column>6.50</column></row><row><column>NaOH25%</column><column>-</column><column>0.94</column><column>0.85</column><column>1.00</column></row><row><column>軟化水</column><column>-</column><column>37.74</column><column>38.30</column><column>34.00</column></row><row><column>ShellsolD40</column><column>26.75</column><column>-</column><column>-</column><column>-</column></row><row><column>PY74Mo隨zo顏料</column><column>40.00</column><column>37.74</column><column>33.97</column><column>40.00</column></row><row><column>消泡劑</column><column>-</column><column>0.28</column><column>0.25</column><column>0.30</column></row><row><column>防腐劑</column><column>-</column><column>0.19</column><column>0.17</column><column>0.20</column></row><row><column>-</column><column>100.00</column><column>100.00</column><column>100.00</column><column>100.00</column></row><table>這些母料的濕度測(cè)試將母料在長(zhǎng)油醇酸樹(shù)脂透明調(diào)漆料中混勻長(zhǎng)油醇酸樹(shù)脂70固體81.7石油溶劑14.6CalO。/。催干劑1.2Co10%催干劑0.4Zrl8。/。催干劑1.7防結(jié)皮劑0.4PY74-母料的添加是按照100g長(zhǎng)油醇酸樹(shù)脂透明調(diào)漆料中添加4g干顏料計(jì)算的。利用這種計(jì)算，載劑和分散劑等的數(shù)量在所有混合物之間是相同的，而只有水量不同。PY42-母料是按照每100g長(zhǎng)油醇酸樹(shù)脂透明漆10g干顏料混合的。PV23-母料是按照每100g長(zhǎng)油醇酸樹(shù)脂透明漆1.3g干顏料混合的。這些混合物用手?jǐn)嚢杈鶆?，?5pm繞線式刮涂棒在聚酯箔上制作刮涂樣并在施用后立即(濕)置于4CTC的濕度箱中干燥一夜。干燥后測(cè)定光澤(60°)。測(cè)試結(jié)果<table><row><column>實(shí)施例</column><column>顏料</column><column>母料中顏料%</column><column>調(diào)濕后光澤</column></row><row><column>比較例1</column><column>PY74</column><column>40.00</column><column>86.1</column></row><row><column>比較例2</column><column>PY74</column><column>37.74</column><column>14.0</column></row><row><column>比較例3</column><column>PY74</column><column>33.97</column><column>61.5</column></row><row><column>比較例4</column><column>PY74</column><column>40.00</column><column>13.0</column></row><row><column>實(shí)施例1</column><column>PY74</column><column>31.07</column><column>27.3</column></row><row><column>實(shí)施例2</column><column>PY74</column><column>28.75</column><column>83.4</column></row><table><table><row><column>實(shí)施例3</column><column>PY74</column><column>33.33</column><column>86.8</column></row><row><column>實(shí)施例4</column><column>PY74</column><column>32.00</column><column>18.6</column></row><row><column>實(shí)施例5</column><column>PY74</column><column>29.08</column><column>80.7</column></row><row><column>實(shí)施例6</column><column>PY74</column><column>33.18</column><column>81.5</column></row><row><column>實(shí)施例7</column><column>PY74</column><column>30.08</column><column>80.5</column></row><row><column>實(shí)施例8</column><column>PY74</column><column>36.77</column><column>64.6</column></row><row><column>實(shí)施例9</column><column>PY74</column><column>35.37</column><column>61.8</column></row><row><column>實(shí)施例10</column><column>PY74</column><column>36.37</column><column>62.5</column></row><row><column>實(shí)施例11</column><column>PY74</column><column>37.77</column><column>63.2</column></row><row><column>實(shí)施例12</column><column>PY74</column><column>25.81</column><column>68.9</column></row><row><column>實(shí)施例13</column><column>PY74</column><column>26.73</column><column>66.2</column></row><row><column>實(shí)施例14</column><column>PY74</column><column>25.73</column><column>67.2</column></row><row><column>實(shí)施例15</column><column>PY74</column><column>32.50</column><column>81.2</column></row><row><column>實(shí)施例16</column><column>PY74</column><column>32.00</column><column>82.2</column></row><row><column>實(shí)施例17</column><column>PY-74</column><column>27.77</column><column>67.7</column></row><row><column>實(shí)施例18</column><column>PY-74</column><column>28.57</column><column>68.2</column></row><row><column>實(shí)施例33</column><column>PY74</column><column>32.00</column><column>65.9</column></row><row><column>實(shí)施例34</column><column>PY74</column><column>32.00</column><column>67.8</column></row><row><column>實(shí)施例35</column><column>PY74</column><column>32.00</column><column>66.3</column></row><row><column>實(shí)施例39</column><column>PY74</column><column>36.1</column><column>83.6</column></row><row><column>實(shí)施例40</column><column>PY74</column><column>36.37</column><column>83.0</column></row><row><column>實(shí)施例40a</column><column>PY42</column><column>50.75</column><column>85.7</column></row><row><column>實(shí)施例40b</column><column>PV23</column><column>10+15</column><column>83.1</column></row><row><column>實(shí)施例42</column><column>PV23</column><column>10+15</column><column>80.3</column></row><row><column>實(shí)施例43</column><column>PV23</column><column>10+15</column><column>79,8</column></row><row><column>實(shí)例44</column><column>PV23</column><column>10+15</column><column>78,3</column></row><row><column>實(shí)施例45</column><column>PV23</column><column>10+15</column><column>78,1</column></row><row><column>實(shí)施例46</column><column>PV23</column><column>10+15</column><column>79,2</column></row><row><column>實(shí)施例47</column><column>PV23</column><column>10+15</column><column>76，3</column></row><row><column>實(shí)施例48</column><column>PV23</column><column>10+15</column><column>68.3</column></row><row><column>實(shí)施例49</column><column>PV23</column><column>10+15</column><column>84.2</column></row><row><column>實(shí)施例50</column><column>PV23</column><column>10+15</column><column>79,0</column></row><row><column>實(shí)施例51</column><column>PV23</column><column>10+15</column><column>67.1</column></row><row><column>實(shí)施例52</column><column>PV23</column><column>10+15</column><column>84.4</column></row><row><column>實(shí)施例53</column><column>PV23</column><column>10+15</column><column>81,0</column></row><row><column>實(shí)施例54</column><column>PV23</column><column>10+15</column></row><row><column>實(shí)施例55</column><column>PV23</column><column>10+15</column></row><row><column>實(shí)施例56</column><column>PV23</column><column>10+15</column><column>3.4</column></row><row><column>實(shí)施例57</column><column>PV23</column><column>10+15</column><column>3.0</column></row><row><column>實(shí)例58</column><column>PV23</column><column>10+15</column><column>2.6</column></row><row><column>實(shí)施例60</column><column>PV23</column><column>10+15</column><column>86,2</column></row><row><column>實(shí)施例62</column><column>PV23</column><column>10+15</column><column>87,3</column></row><row><column>實(shí)施例64</column><column>PV23</column><column>10+15</column><column>90,4</column></row><row><column>實(shí)施例66</column><column>PV23</column><column>10+15</column><column>88,7</column></row><table>濕度試驗(yàn)結(jié)果證實(shí)，基于本發(fā)明的濕潤(rùn)劑的漆膜，與聚乙二醇濕潤(rùn)劑(比較例2和4)相比，顯示出固化膜的高光澤。PY74:單偶氮類，購(gòu)自Ciba公司或Clanant公司PV23:二噹。秦類，購(gòu)自Ciba公司或Clarmnt公司注顏料％=10%￥23+15%陶土，購(gòu)自Engelhard公司PY42:黃色氧化物，購(gòu)自拜耳公司Nuosperse2000,購(gòu)自Elementis公司HumectantGRB2,購(gòu)自Avecia公司ShellsolD40,購(gòu)自殼牌公司EFKA_6225,購(gòu)自EFKAAdditivesB.V.權(quán)利要求1.加顏料的調(diào)色母料，包含a)穩(wěn)定的顏料；b)可通過(guò)在150～260℃的溫度在一種多不飽和化合物與一種共反應(yīng)物之間進(jìn)行第爾斯-阿爾德反應(yīng)得到的濕潤(rùn)劑化合物，該共反應(yīng)物有化學(xué)式R1XOC-CH＝CH-COXR2或CH2＝CH-COXR3或CH2＝CH(CH3)-COXR3，式中X是氧或-NH-，且式中R1和R2中至少一個(gè)是一種聚醚片斷，R1和R2中任何另一個(gè)是一種聚醚片斷或氫，而R3是一種聚醚片斷。2.按照權(quán)利要求1的加顏料的調(diào)色母料，其中多不飽和化合物是山梨酸(2，4-己二烯酸)、(3-lonone(2,6，6-三甲基環(huán)己烯基-丁烯—2—酮)、月桂烯(7—甲基—3-亞曱基—1,6-辛二烯)。3.按照權(quán)利要求1的加顏料的調(diào)色母料，其中多不飽和化合物是一種不^L和油或/人其得到的一種酯交換油。4.按照權(quán)利要求3的加顏料的調(diào)色母料，其中多不飽和油是桐油或奧氣油或者酯交換的桐油或奧氣油。5.按照權(quán)利要求1的加顏料的調(diào)色母料，其中該濕潤(rùn)化合物是式I的化合物<formula>formulaseeoriginaldocumentpage2</formula>式中a、b和c各自獨(dú)立地是0或1,先決條件是當(dāng)b和c為0時(shí)a為1;Y當(dāng)a、b和c為1時(shí)是—CH2-;且Y當(dāng)a為l而b和c為O時(shí)是d-C2o烷基或一種聚醚片斷；R4是<formula>formulaseeoriginaldocumentpage3</formula>X是氧或-NH-；R5和R6是氫或R4或多不飽和脂肪酸片斷；R！和R2中至少一個(gè)是一種聚醚片斷，且R}和R2中任何另一個(gè)是一種聚醚片斷或氫；R3是一種聚醚片斷；R7是氫或甲基；W是_(CH2)P-或-(CH2)p,-CO(CH2)q-;n是020、較好4~10;m是(2n-2)~2n;p是1~20、較好4~10;p，是1~20、較好24;q是1~20、較好4~10。6.按照權(quán)利要求1中所述的可通過(guò)在150260。C的溫度在一種多不飽和化合物與一種共反應(yīng)物之間進(jìn)行第爾斯-阿爾德反應(yīng)得到的化合物作為濕潤(rùn)劑的用途，該共反應(yīng)物有式RJOC-CH=CH-COXR2或CH2=CH_COXR3或CH2=CH(CH3)-COXR3，式中X是氧或-NH-,且式中Ri和R2中至少一個(gè)是一種聚醚片斷，R和R2中任何另一個(gè)是一種聚醚片斷或氬，和R3是一種聚醚片斷。7.權(quán)利要求5中定義的式I的化合物作為濕潤(rùn)劑的用途。全文摘要本發(fā)明涉及加顏料的調(diào)色母料，包含a)穩(wěn)定的顏料；b)濕潤(rùn)劑化合物，該化合物可通過(guò)在150～260℃的溫度的一種多不飽和化合物與一種助反應(yīng)物之間進(jìn)行第爾斯-阿爾德反應(yīng)得到，該助反應(yīng)物有化學(xué)式R₁XOC-CH＝CH-COXR₂或CH₂＝CH-COXR₃或CH₂＝CH(CH₃)-COXR₃，式中X是氧或-NH-，且式中R₁和R₂中至少一個(gè)是聚醚片斷，R₁和R₂中任何另一個(gè)是聚醚片斷或氫，R₃是一個(gè)聚醚片斷。文檔編號(hào)C09D17/00GK101175828SQ200680016957公開(kāi)日2008年5月7日申請(qǐng)日期2006年5月8日優(yōu)先權(quán)日2005年5月18日發(fā)明者F·O·H·皮魯恩格,L·A·恩格爾布萊克特,R·范伯赫門(mén)申請(qǐng)人:西巴特殊化學(xué)品控股有限公司